Prelab 2
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Dec 6, 2023
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Avery O’Brien
CHEM 343-76
Prelab Questions for Lab 2 (10 points)
1.
Heba and her friend Nora have the same unknown solid. Heba has progressed a little
faster with the purification process, but now she is standing around twiddling her
thumbs because no crystals are forming, even over an ice bath. Nora decides that Heba’s
problem is too much solvent. Determined not to have the same problem, Nora uses a
minimal volume of hot solvent to dissolve her compound before doing the gravity
filtration step. She begins to pour her hot solution into the filter cone of a long-stemmed
funnel and ….is that missed impurities sprouting up on the funnel walls? Why so shiny?
Explain what Nora did wrong and how to fix the problem. List 2 things she should do.
3pts
Nora used a long-stemmed funnel when she should have used a stemless funnel when
performing the gravity filtration. In order to get the crystals off the funnel walls she could use
distilled water to try and release the crystals from the side. Additionally, Nora could use a clean
microspatula to free the crystals from the walls.
2.
Neel’s unknown solid 1) dissolves in hot ethanol, 2) is essentially insoluble in hexane, and
3) is insoluble in cold water, but sparingly soluble in warm water. Outline a
recrystallization procedure. 4pt
A mixed solvent will have to be used for recrystallization. First Neel should dissolve his unknown
solid in hot ethanol. Then after letting the solution cool and begin to crystallize, cold water
should be added to encourage more crystal growth, making the solution cloudy. Then a gravity
filtration and vacuum filtration can be performed to completely isolate the crystals. Afterwards
the crystals can be washed to finish the purification.
3.
Where is the capillary tube placed for the microscale boiling point determination and
how is it orientated? What is collected in the capillary tube? 3 pts
The capillary tube is placed in the test tube for microscale boiling point determination and is
oriented so the opening of the capillary tube is pointing towards the bottom of the test tube
and is upside down. When the boiling point is met, liquid will collect in the capillary tube
Related Questions
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5. As a home health nurse you need to help a client make…
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You are presented with the following prescription: Rx Drug Y 175 mg Witepsol H15 q.s. Supply 6 suppositories (using 3 g nominal moulds) When using Witepsol H15, moulds will hold 1.06 times their nominal weight. The displacement value of Drug Y in Witepsol H15 is 1.1. Calculate the mass of Witepsol H15 required to prepare this product. Give your answer to two decimal places
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Chap12
Q2&3
Needed to be solved both Question correctly in 30 minutes and get the thumbs up please show me hundred percent efficient solution In the order to get positive feedback
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-Ridge regression will usually have non-zero coefficients for both predictors.
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Density of solution:Trial 1: 1.2 g/mLTrial 2: 1.2 g/mLTrial 3: 1.2 g/mL
Average density = 1.2 g/mL
What is the relative average deviaion, %?
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ANSWER IF DIRECTLY PROPORTIONAL, INDIRECTLY PROPORTIONAL, OR NO CORRELATION
1. Concentration of croscarmellose vs. dissolution rate
2. Concentration of magnesium stearate vs. degree of bioavailability
3. Concentrations of sodium lauryl sulfate vs. dissolution rate (presuming that it is at excessive levels)
4. Viscosity of a syrup vs. dissolution rate
5. Concentrations of acacia gum in a suspension vs. rate of absorption
6. Degree of ionization vs. hydrophilic property
7. Particle size vs. dissolution rate
8. Concentration of polyethylene glycol in a drug product vs. dissolution rate
9. Concentration of buffering agents with a weak acid vs. dissolution rate
10. Tablet coating vs. absorption rate
11. Number of free energy vs. stability of the crystalline form
12. contact time of patch to the skin vs drug absorbed
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General Chemistry for Engineers
Lesson: Chemical Kinetics
Directions: Answer the following problems by showing the complete solution. In return, I will give you a good and high rating. Thank you so much!
Note: Please be careful with the units and measurements in calculations. Thank you!
No. 1-2.
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19 g of unknown organic sample was dissolve in 640 mL of Dicloromethane (DCM). The boiling point of benzene was increased by 3.78oC. Determine the molecular weight of the unknown sample?
Kb of DCM = 2.42oC/m
Bb of benzene = 39.6 oC
density of benzene = 1.33 g/mL at 25 °C
Round your answer to the nearest whole number, no units required.
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Gypsum (CaSO4) is one of common precipitants in brackish water desalination processes.
CaSO4 ⇋ Ca2+ + SO42- Ksp = 10-4.6Assume a water containing: [Ca2+] = 10-2.1 M; [SO42-] = 10-3.2 M.(a) Find Qsp or IAP for the given water.
(b) Find the solubility index (SI) and determine whether CaSO4 is under, super, or at saturation in the water.
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What is the role of water in Baeyer's Test?
Negative Control
Positive Control
Polar Control
Neutral Control
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part A
1. Concentration of Known NiCl2 Stock Solution
___500________ mM
Tube Number
Blank
#1
#2
#3
#4
#5
2. Volume of Known NiCl2 Stock Solution Pipetted Into Tube
0.00 mL
1.50 mL
3.00 mL
4.50 mL
6.00 mL
7.50 mL
3. Volume of Distilled Water Pipetted Into Tube
11.00 mL
9.50 mL
8.00 mL
6.50 mL
5.00 mL
3.50 mL
4. Total Volume of Solution In Tube
11.00 mL
11.00 mL
11.00 mL
11.00 mL
11.00 mL
11.00 mL
5. Diluted Concentration of NiCl2 In Tube
-----------
68.2 mn
136mn
204mn
273mn
341mn
1. Equation for the Best-Fit Straight Line
Y=3822x+4.7446
2. Absorbance at λmax for Diluted Unknown
0.87
3. Concentration of NiCl2 in Diluted Unknown
25.693 mM
Determine the dilution factor for your diluted unknown U1 based on how you prepared the solutions in Part A. Record this on your report sheet in Part D #4.
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The gravimetric factor used to express CoCBr6·H20 in a sample that is finally weighed as PbClBr is
choose below:
FW PbClBr / 6 x FW CoCBr6·H20
FW CoCBr6·H20 / FW PbClBr
FW CoCBr6·H20 / 6 x FW PbClBr
6 x FW PbClBr / FW CoCBr6·H20
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please help with subpart 4, I'm uploading first 3 answer for your convenience.
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Find ΔmixG, ΔmixS, and ΔmixH for mixing 100 g of benzene with 100 g of toluene at 20oC and 1 atm. Assume an ideal solution.
Please answer fast i give you upvote.
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Qc10&12
Solve both in the order to get positive feedback please show me hundred percent efficient solution
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Activity 2: Syrup
Formula
Sucrose ___
Purified water ___
To make 30ml
Procedure:
A. Agitation without heat:
B. Solution by heat:
C. Percolation:
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1) How many milliliters of 70% ethanol and 20% ethanol must be mixed to prepare 500ml of 30% ethanol?
2) A gaseous blend of nitric oxide and nitrogen (NOmax) contains 0.09% v/v nitric oxide (NO) and 99.92% v/v nitrogen. Express the strength of nitric oxide in PPM (round to whole number)
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(6.65x10^5)/(6.60x10^-6) (3.73x10^8)
Please Calaculition.
Only typed solution
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Activity 2: Syrup
Sucrose ___
Purified water ___
To make 30ml
Procedure:
A. Agitation without heat:
B. Solution by heat:
C. Percolation:
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Based on your value of Ksp1 what is the solubility of borax in the room temperature solution?
Trial 1: 0.0141 T2: 0.015 AVG: 0.0139
Temp: 293.15K
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4- Please I want answer sub-parts (c) and (d) with steps and clear typing or hand writing. Many thanks
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a
0.784
b
0.870
c
1.149
d
1.275
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Standardization of Sodium Thiosulfate Solution
Primary Standard used: Potassium Dichromate
Formula mass of 1o standard: __________________
% Purity of 1o standard: 99.80%
Trials
1
2
3
Weight of K2Cr2O7 (g)Weight of K2Cr2O7 (g)
0.0315
0.0331
0.0380
Final Volume Reading Na2S2O3 (ml)
27.50
27.50
34.90
Initial Volume Reading Na2S2O3 (ml)
1.10
0.00
1.00
Net Volume Na2S2O3 used (ml)
Molarity of Na2S2O3
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1. What group of organic compounds does caffeine belong to?
2. Draw the structure of caffeine as a line formula. Redraw the structure of caffeine,showing all carbon and hydrogen atoms.
3. What is the molecular formula for caffeine? Use the molecular formula of caffeine tocalculate its molecular weight.
4. What does it mean for two solvents to be immiscible?
5. On the report sheet, you calculated your percent recovery of caffeine.
a. If your percent was less than 90%, give at least one reason why it was less.
b. A group of students have their percent yield more than 100%, give at least one reasonwhy it was more than 100%. Do NOT simply say “human error.” Be specific about the typesof errors (human or otherwise) that may have occurred, leading to a recovery more than eorequal to 100% (Is this possible Why?)
6. Based on what you observed during this experiment, is dichloromethane denser OR lessdense than water? Explain your reasoning.
7. Based on what…
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Add a trendline (polynomial, 3rd order should work) to each of the coexistence lines separately.
Scale the plot appropriately and use the graph to answer the questions.
Then complete E5C.1(b)
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1. Assume your analytical method requires a volume flow rate of 2.5 lpm. The required volume is 25 liters to 125 liters. Employees work four hours before lunch and four hours after lunch. What will be your sampling plan? Please explain fully.
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Solve for the (E) Increase in boiling point, (F) Molecular Weight of urea (experimental), (G) Molecular Weight of urea (calculated), and (H) Percent Error.
Given:
A. Weight of urea = 2.83 g
B. Weight of water = 10 g
C. Boiling point of distilled water = 98°C
D. Boiling point of urea solution = 101°C
E. Increase in boiling point = ?
F. Molecular Weight of urea (experimental) = ?
G. Molecular Weight of urea (calculated) = ?
H. Percent Error = ?
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1. You give your home health patient an unopened 500-mL bottle of guaifenesin and tellthem to take 2 teaspoons 4 times a day as ordered. They ask you how long the bottlewill last.
2. You are shadowing a nurse during a clinical who receives an order to adjust the infusionrate of a pump so that 1.6 mg of lidocaine are being delivered per minute. Hanging is a100 mL piggyback containing 0.4 grams lidocaine, a 0.4% solution. How many mL perhour should the piggyback be set to deliver? How long will the piggyback last?
3. Phenobarbital 180 mg/m 2 /24 hours given every eight hours is ordered for a childwhose BSA (body surface area) is 0.29 m 2 . How many mg will you need if the child willbe on the medication for 10 days?
4. You are going to mix a 1:10 bleach solution with water to make 500 mL of a 1:35 bleachsolution. How much 1:10 bleach solution should you use?(I recommend using the C1V1=C2V2 formula)
5. As a home health nurse you need to help a client make…
arrow_forward
help me asap pls for number 5 less than 15 mins
arrow_forward
When I balance it out with 2,15,10 and 10. Does not work I'm confused pls help.
arrow_forward
You are presented with the following prescription: Rx Drug Y 175 mg Witepsol H15 q.s. Supply 6 suppositories (using 3 g nominal moulds) When using Witepsol H15, moulds will hold 1.06 times their nominal weight. The displacement value of Drug Y in Witepsol H15 is 1.1. Calculate the mass of Witepsol H15 required to prepare this product. Give your answer to two decimal places
arrow_forward
Chap12
Q2&3
Needed to be solved both Question correctly in 30 minutes and get the thumbs up please show me hundred percent efficient solution In the order to get positive feedback
arrow_forward
When two predictors are highly correlated, which of the following statements is true?
-Ridge regression will usually have non-zero coefficients for both predictors.
-Ridge Regression will drive coefficients to zero for both features.
-Lasso regression will usually have non-zero coefficients for both predictors.
-Elastic net will usually have non-zero coefficients for both predictors
select the correct option
arrow_forward
Density of solution:Trial 1: 1.2 g/mLTrial 2: 1.2 g/mLTrial 3: 1.2 g/mL
Average density = 1.2 g/mL
What is the relative average deviaion, %?
arrow_forward
ANSWER IF DIRECTLY PROPORTIONAL, INDIRECTLY PROPORTIONAL, OR NO CORRELATION
1. Concentration of croscarmellose vs. dissolution rate
2. Concentration of magnesium stearate vs. degree of bioavailability
3. Concentrations of sodium lauryl sulfate vs. dissolution rate (presuming that it is at excessive levels)
4. Viscosity of a syrup vs. dissolution rate
5. Concentrations of acacia gum in a suspension vs. rate of absorption
6. Degree of ionization vs. hydrophilic property
7. Particle size vs. dissolution rate
8. Concentration of polyethylene glycol in a drug product vs. dissolution rate
9. Concentration of buffering agents with a weak acid vs. dissolution rate
10. Tablet coating vs. absorption rate
11. Number of free energy vs. stability of the crystalline form
12. contact time of patch to the skin vs drug absorbed
arrow_forward
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Lesson: Chemical Kinetics
Directions: Answer the following problems by showing the complete solution. In return, I will give you a good and high rating. Thank you so much!
Note: Please be careful with the units and measurements in calculations. Thank you!
No. 1-2.
arrow_forward
19 g of unknown organic sample was dissolve in 640 mL of Dicloromethane (DCM). The boiling point of benzene was increased by 3.78oC. Determine the molecular weight of the unknown sample?
Kb of DCM = 2.42oC/m
Bb of benzene = 39.6 oC
density of benzene = 1.33 g/mL at 25 °C
Round your answer to the nearest whole number, no units required.
arrow_forward
Gypsum (CaSO4) is one of common precipitants in brackish water desalination processes.
CaSO4 ⇋ Ca2+ + SO42- Ksp = 10-4.6Assume a water containing: [Ca2+] = 10-2.1 M; [SO42-] = 10-3.2 M.(a) Find Qsp or IAP for the given water.
(b) Find the solubility index (SI) and determine whether CaSO4 is under, super, or at saturation in the water.
arrow_forward
What is the role of water in Baeyer's Test?
Negative Control
Positive Control
Polar Control
Neutral Control
arrow_forward
arrow_back_ios
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arrow_forward_ios
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