5. How would you convert the following compounds into butanoic acid using reagents from the table? None require more than 2 steps. a. Butuanal b. 1-butene c. 1-bromopropane d. 1-chlorobutane Reagents e KOtBu i 1. BH3/THF 2. H₂O₂/ NaOH b KMnO4 / H3O+ f NaOH j 1. CO₂ 2. H3O+* с 1. LiAlH4 g conc. HCI k NaCN 2. H3O+ d H3O*, heat h Mg / dry ether | 1. Li 2. Cul
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- Order the following acids with respect to increasing acidity: I. Fluoroacetic acid II. Chloroacetic acid III. 3-chloropropanoic acid IV. Propanoic acidWrite TRUE if the statement is correct, FALSE if otherwis 42. The end point in the procedure of acid value is the disappearance of the pink color.43. Blank determination is employed in the determination of the Koettsdorfer number.44. Saponification is the alkaline hydrolysis of fatty oils which leads to formation of soaps.45. Esters are composed of carboxylic acids and alcohol.Answer questions a-c about the Bronsted acid-base reaction below using the identifying letters A-D below each structure.A table of pKa values for various organic and inorganic acids can be found in the references section.for parts 1 and 2 a) The weaker acid is b) Its conjugate base is c) The species that predominate at equilibrium are (two letters, e.g. AC)
- On the axes below, sketch the graphs which show the result of adding: 0.1M NaOH to 25cm3 of 0.1M ethanoic acid. 0.1M NaOH to 25cm3 of 0.1M H2SO4Arrange the acids below in order of predicted decreasing strength (i.e., from strongest to weakest). A H3NB HClC H3PD H2SE H3AsSHOW COMPLETE SOLUTIONS Q3. Which isolate has A260/280 ratio of above 2.0?
- Would the acid chloride add ortho para or meta?In a titration of methylamine CH3NH2 (pKb = 3.34) with HNO3, which of the following color indicator is preferred? You may refer to the lecture slides to find their transition range. Erythrosin B Alizarin m-Nitrophenol Bromthymol blue Phenol RedAccording to the Evan's pKa table, phenol has a pKa of 9.95. p-Nitro and m-nitrophenol have pKas of 7.14 and 8.35 respectively. Using resonance structures, explain the observed trends in the acidity of these molecules.
- Write equations for the following acid-base reactions. Label the conjugate acids and bases, and show any inductive stabilization. Predict whether the equilibrium favors the reactants or products. Try to do this without using a table of pKa values, (a) CH3CH2OH + CH3NH- (b) F3CCOONa + Br3C¬COOH(c) CH3OH + H2SO4 (d) NaOH + H2S(e) CH3NH3+ + CH3O- (f) BrCH2CH2OH + F3C¬CH2O-(g) NaOCH2CH3 + Cl2CHCH2OH (h) H2Se + NaNH2(i) CH3CHFCOOH + FCH2CH2COO- (j) CF3CH2O- + FCH2CH2OHBase from the illustration: 1. Which compound/s will test positive in Baeyer’s test? 2. Which compound/s will produce an orange precipitate upon reaction with 2,4-DNPH? 3. Which compound/s will test positive in the Iodoform test? 4. Which compound/s will produce a brick-red precipitate upon reaction with Fehling’s reagent (CuSO4, tartrate, NaOH)? 5.Table of unknown carboxylic acidsMeltingRange Acid MW MeltingRange Acid MW77-78 phenylacetic 136.15 152-153 adipic (hexanedioic) *** 146.1483-85 2,2-dimethylglutaric 160.17 155-157 3-chlorobenzoic 156.5786-88 4-methoxyphenylacetic 166.17 155-158 3-bromobenzoic 201.0298-100 o-anisic (2-methoxybenzoic) 152.15 157-159 4-chlorophenoxyacetic 186.59100-102 3,3-dimethylglutaric 160.17 158-160 salicylic (2-hydroxybenzoic) 138.12103-105 o-toluic (2-methylbenzoic) 136.2 159-162 4-chloro-3,5-dinitrobenzoic 246.56122-123 benzoic 122.12 162-163 2-iodobenzoic 248.02128-131 thiodiglycolic *** 150.15 180-182 p-toluic (4-methylbenzoic) 136.15131-134 3,3’-thiodipropionic *** 178.21 182-185 p-anisic (4-methoxybenzoic) 152.15133-134 trans-cinnamic 148.16 187-190 succinic (butanedioic) *** 118.09139-140 2-chlorobenzoic 156.57 210-211 phthalic (benzene-1,2-dioic) *** 166.14140-142 3-nitrobenzoic 167.12 215-217 4-hydroxybenzoic 138.12148-150 2-bromobenzoic 201.02 239-241 4-chlorobenzoic 156.57144-148…